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Laine left Wisconsin at the age of 16, moving to Florida. While living in Florida, she did traditional modeling for swimwear and sunglass companies and print media. She started to pose nude and perform in adult movies in 2002 and since then has appeared in over 100 films. 

Although a natural brunette, in some of her work her hair is dyed red. In the beginning, Laine did several bondage videos and one blowjob video, but what she does now are solo and lesbian scenes.  Charlie has been paired up with some of the most beautiful women in porn and they produce some of the hottest girl-girl scenes ever recorded. Some of her very first shoots were with the world renowned director, Ed Powers.

She was the Penthouse Pet of the Month for February 2006, and has appeared in magazines Hustler and Barely Legal.

In 2006, she appeared on The Howard Stern Show, where she promoted her Penthouse Letters cover and talked about her career and mentioned being dumped by actor Rey-Phillip Santos for pursuing a career in the adult film industry.